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Excess heat capacities and excess volumes of (an n-alkylalkanoate + heptane or decane or toluene)

✍ Scribed by E. Jiménez; L. Romanı́; Emmerich Wilhelm; G. Roux-Desgranges; J.-P.E. Grolier

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
304 KB
Volume
26
Category
Article
ISSN
0021-9614

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Excess molar volumes were determined over the whole composition range for (dimethyl carbonate, or diethyl carbonate + n-heptane) at the temperatures (278.15, 288.15, 298.15, and 308.15) K, and at atmospheric pressure with a vibrating-tube densimeter. In addition, a differential scanning calorimeter

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Excess molar volumes V E m and excess molar heat capacities C E p,m were determined for mixtures of benzonitrile with chlorobenzene, or benzene, or toluene at the temperatures 298.15 K and 303.15 K. For all the systems the values of V E m were negative over the whole range of compositions and values

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✍ M. Pintos-Barral; R. Bravo; G. Roux-Desgranges; J.-P.E. Grolier; Emmerich Wilhel 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 213 KB

## Excess molar heat capacities C E p,m at constant pressure have been measured, as a function of mole fraction x at the temperature T = 298.15 K and atmospheric pressure, for eight liquid mixtures consisting of an n-alkylalkanoate and a highlybranched alkane {i.e. 2,2,4-trimethylpentane (isooctan