Excess molar enthalpies and excess molar heat capacities at T = 298.15 K were determined for {xCHCl3 Both experimental properties were represented by a Redlich-Kister type equation. The large negative values of the excess enthalpies and the positive values of the excess heat capacities observed in
Excess molar volumes and excess molar heat capacities of (benzonitrile + chlorobenzene, or benzene, or toluene) at temperatures of 298.15 K and 303.15 K
β Scribed by Reiji Tanaka; Toru Nakamichi
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 220 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0021-9614
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β¦ Synopsis
Excess molar volumes V E m and excess molar heat capacities C E p,m were determined for mixtures of benzonitrile with chlorobenzene, or benzene, or toluene at the temperatures 298.15 K and 303.15 K. For all the systems the values of V E m were negative over the whole range of compositions and values of (1V E m /1T) were negative. The values of C E p,m were all positive for the mixtures with chlorobenzene and toluene, while the sign for the mixture with benzene changed from positive to negative with increasing mole fraction of benzonitrile. The magnitudes of (1C E p,m /1T) were small, and the sign depended on the system.
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