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Excess Gibbs free energies of (hexane + butan-2-ol) and of (cyclohexane + butan-2-ol) at the temperatures (323.15, 338.15, and 348.15) K

✍ Scribed by M.E. Araujo; M.R.W. Maciel; A.Z. Francesconi

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
121 KB
Volume
25
Category
Article
ISSN
0021-9614

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The densities of the mixtures (hexane or cyclohexane+propan-2-ol or butan-2-ol) at the temperatures (288.15 and 298.15) K have been measured using a vibrating-tube densitometer. Excess molar volumes V E m were calculated. The results were described by means of the ERAS model. All mixtures exhibit po

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Excess volumes of (1,2-dichloroethane or 1,2-dibromoethane + each of several isomers of butanol) have been determined from density measurements at the temperatures \(298.15 \mathrm{~K}\) and \(313.15 \mathrm{~K}\) using an Anton-Paar dersimeter. The results show that excess volumes are positive over

Excess molar enthalpies and excess molar
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Excess molar enthalpies H E m and excess molar volumes V E m have been determined for (butane+propan-1-ol) at temperatures (298.15, 323.15, and 348.15) K and at pressures (5, 10, and 15) MPa. The H E m results and the excess molar heat capacity C E p,m are positive, while V E m (x) is s-shaped, chan