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Excess enthalpies of (aniline + butan-1-ol) and of (aniline + butan-1-ol + benzene) at the temperature 298.15 K

✍ Scribed by Isamu Nagata


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
115 KB
Volume
25
Category
Article
ISSN
0021-9614

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## Excess molar enthalpies of {xC6H5NH2 , measured with a flow microcalorimeter or an isothermal dilution calorimeter at the temperature 298.15 K, are reported. The experimental results have been correlated with polynomial equations and the UNIQUAC formalism having binary and ternary parameters. 7

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Excess molar enthalpies \(H_{\mathrm{m}}^{\mathrm{E}}\) and excess molar volumes \(V_{\mathrm{m}}^{\mathrm{E}}\) have been determined for \(\left\{x \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{CH}_{3}+(1-x) \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{CH}_{2} \mathrm{OH}\right

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Excess molar enthalpies of \(\left\{x_{1} \mathrm{CH}_{3} \mathrm{OH}+x_{2} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{2}+\left(1-x_{1}-x_{2}\right) \mathrm{CH}_{3} \mathrm{OCH}_{3}\right\}\), measured with a flow microcalorimeter at the temperature \(298.15 \mathrm{~K}\), are reported. The experime

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Excess volumes of (1,2-dichloroethane or 1,2-dibromoethane + each of several isomers of butanol) have been determined from density measurements at the temperatures \(298.15 \mathrm{~K}\) and \(313.15 \mathrm{~K}\) using an Anton-Paar dersimeter. The results show that excess volumes are positive over

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, measured with a flow microcalorimeter at the temperature 298.15 K, are reported. The experimental results have been correlated with polynomial equations and compared with those calculated from an association model based on mole-fraction statistics having binary and ternary parameters.