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EXAMINATION OF THE IODOFORM AND SCHMIDT REACTIONS OF ACETONE-1-C 14 FOR ISOTOPE EFFECTS

✍ Scribed by Ropp, Gus A.; Ronner, William A.; Clark, Marion T.; Raaen, Vernon F.


Book ID
127086161
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
244 KB
Volume
76
Category
Article
ISSN
0002-7863

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Isotope effects and mechanism in the bas
✍ Agnes Pulay; Arthur Fry πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 244 KB

In the base-promoted dehydrochlorinT;ion of I.i-dichloro-2,2-diphenyiethane-l-C and its D-nitro analog, the isotope effects, k/ k, are 1.045 and 1.024, respectively. These results support an.Elcb-like E2 mechanism for both elimination reactions.