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Carbon-14 isotope effects in the addition of 2,4-dinitrobenzenesulfenyl chloride to styrene-1-14C and styrene-2-14C

โœ Scribed by Kanska, Marianna; Fry, Arthur

Book ID
125966832
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
430 KB
Volume
104
Category
Article
ISSN
0002-7863

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Carbon-14 kinetic isotope effects and mechanisms of addition of 2,4-dinitrobenzenesulfenyl chloride to substituted styrenes in the presence of lithium perchlorate
โœ Marianna Kanska; Arthur Fry ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 246 KB

The k/ak isotope effect for addition of ArSCl to R-methylstyrene is small and unchanged by addition of LiClO ; k/'k is high and unchanged. k/Bk values are liigh and uncha:ged, while k/'k increases from For styrene and R-chlorostyrene -1.025 to -1.04. R-Methyl-