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Carbon-14 and deuterium isotope effects during the [2 + 2] cycloaddition of diphenylketene to styrene

โœ Scribed by Collins, Clair J.; Benjamin, Ben M.; Kabalka, George W.

Book ID
125986081
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
284 KB
Volume
100
Category
Article
ISSN
0002-7863

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The k/ak isotope effect for addition of ArSCl to R-methylstyrene is small and unchanged by addition of LiClO ; k/'k is high and unchanged. k/Bk values are liigh and uncha:ged, while k/'k increases from For styrene and R-chlorostyrene -1.025 to -1.04. R-Methyl-