Carbon-14 kinetic isotope effects and mechanisms of addition of 2,4-dinitrobenzenesulfenyl chloride to substituted styrenes in the presence of lithium perchlorate

✍ Scribed by Marianna Kanska; Arthur Fry

• Publisher: Elsevier Science
• Year: 1986
• Tongue: French
• Weight: 246 KB
• Volume: 27
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)85133-3

✦ Synopsis

The k/ak isotope effect for addition of ArSCl to R-methylstyrene is small and unchanged by addition of LiClO ; k/'k is high and unchanged. k/Bk values are liigh and uncha:ged, while k/'k increases from For styrene and R-chlorostyrene -1.025 to -1.04. R-Methyl-