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EXAFS and x-ray diffraction study of a mixed NiCl2CoCl2 solution

✍ Scribed by A. Corrias; A. Musinu; G. Pinna

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 453 KB
Volume: 120
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)87061-5

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✦ Synopsis

A mixed solution of CoCl1 and NiC12 (with concenlrakx of each cnGon equal to 0.5 M) enriched in Cl-up IO a Cl-/cation atomic n~io or 7. has been examined by X-ray dirfrxcion and EXAFS spectroscopy. The global inrormnlion nboul the inLeracGons or the two tr;lnsilion mrrals obmined by X-ray diffraction is in qreemen~ with results obnincd independenrly bv EXAFS for cobah and nickel. A stronarr Iendency of Ihe Co?' ion wilh rcspert to Ni'+ ICI form chloro complexes is seen b; EXAFS.

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