LiBr aqueous solutions were invest&ted by X-ray diffraction in order to study the strucrure of hydrated Br-ions. A simple model describing the coordination sound the ions only in terms of newest-neiabour intcnctions
X-ray diffraction study of a “three-ion” aqueous solution
✍ Scribed by R. Caminiti; G. Licheri; G. Piccaluga; G. Pinna
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 375 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
X-ray diffraction data on an aqueous solution 2 M in
MgC12 and CaCI2 are shown to be consistent with octahedral coordinations for the three ions as already found in solutions of single electrolytes. The rare-gas-like ion hydration thus appears not affected by the presence of other ions independently hydrated.
📜 SIMILAR VOLUMES
Pure water and HCI aqueous solutions 1N and 4.3N at 2S°C were investigated. The radial distribution functions (RDF) of the solutions show the same general feature as the water RDF; the first peak becomes however broader and shifts to larger R values BS expected because of OH-Cl-interaction. The res
A computer controlled X-ray diffraction system utilizing position sensitive photon counting techniques that is capable of investigating, in situ, structure at the solid/liquid interface, particularly that between an electrode and an electrolyte solution, is described. The application of this techniq