Evidence for tunneling in the reaction O(3P)+HD
โ Scribed by Daniel C. Robie; Sivaram Arepalli; Nathan Presser; Theofanis Kitsopoulos; Robert J. Gordon
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 320 KB
- Volume
- 134
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
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Rate coefficients, in units of 10-~0 cm 3 molecule-~ s-~, for the O(~D) reactions with H2, D 2 and HD at 298 K were determined to be 1.2 \_\_\_ 0.1, 1.1 + 0.1, and 1.2 + 0.1, respectively. The H atom yield in the O(~ D) + HD reaction, relative to that in the O(ID) + H 2 reaction, was measured to be
The O(3P) + CION reaction has been studicd in a fast flow system over the temperature range from 213 to 295 K, using the air-aftereIow technique for the detection of oxygen atoms under pseudo first order conditions. A value of (3.4 z 0.6) x 10-" exp[(-840 + 60)/T] cm3 molecule-' s-' has been obtaine
## Strong oscillations m the reactivity as a function of collision energy were found in collinear quasiclassical trajectory calculations for the reaction 0( 3 P)+ HCl( v = 0) + OH + Cl. Oscillations were also observed m 3D calculations for IICl( v = 0, J = 0) under the special conditions of near-z