Evidence for triplet CF2 formation in the O(3P) + C2F4 reaction
โ Scribed by David S.Y. Hsu; M.C. Lin
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 422 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The kinetics of the reactions O( 3 P) ฯฉ CF 2 "CCl 2 and O( 3 P) ฯฉ CF 3 CF "CF 2 were studied at room temperature in a discharge flow tube system. The overall rate constants based on the measured afterglow reactions were (3.10 ฯฎ 0.40) ฯซ 10 ฯช13 and (3.00 ฯฎ 0.60) ฯซ 10 ฯช14 cm 3 molecule ฯช1 s ฯช1 , respec
N-sulfinylacylamides R-C(ฯญO)-NฯญSฯญO react with (CF 3 ) 2 BNMe 2 (1) to form, by [2ฯฉ4] cycloaddition, six-membered rings cyclo-(CF 3 ) 2 B-NMe 2 -S(ฯญO)-NฯญC(R)-O for R ฯญ Me (2), t-Bu (3), C 6 H 5 (4), and p-CH 3 C 6 H 4 (5) while N-sulfinylcarbamic acid esters R-O-C(ฯญO)-NฯญSฯญO react with 1 to yield mixt
Gases which are known to react rapidly with CH (X 'II) are added to low pressure mixtures of oxygen atoms and acetylene while monitoring chemi-ion formation. Addition of CH, and N,O, which do not react with oxygen atoms at room temperature, rapidly quench part of the chemi-ion formation, but further