Evidence for the Involvement of Silver Nanoclusters during the Wolff Rearrangement of α-Diazoketones †
✍ Scribed by Sudrik, Surendra G.; Maddanimath, Trupti; Chaki, Nirmalya K.; Chavan, Sambhaji P.; Chavan, Subhash P.; Sonawane, Harikisan R.; Vijayamohanan, K.
- Book ID
- 127044719
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 117 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1523-7060
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## Abstract In this work we report the unique electrocatalytic role of benzoic acid protected silver nanoclusters (Ag~__n__~, mean core diameter 2.5 nm) in the Wolff rearrangement (Scheme 1) of α‐diazoketones. More specifically, the presence of a Ag~__n__~^0^/Ag~__n__~^+^ redox couple facilitates a
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