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Evidence for the Involvement of Silver Nanoclusters during the Wolff Rearrangement of α-Diazoketones †

✍ Scribed by Sudrik, Surendra G.; Maddanimath, Trupti; Chaki, Nirmalya K.; Chavan, Sambhaji P.; Chavan, Subhash P.; Sonawane, Harikisan R.; Vijayamohanan, K.


Book ID
127044719
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
117 KB
Volume
5
Category
Article
ISSN
1523-7060

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## Abstract In this work we report the unique electrocatalytic role of benzoic acid protected silver nanoclusters (Ag~__n__~, mean core diameter 2.5 nm) in the Wolff rearrangement (Scheme 1) of α‐diazoketones. More specifically, the presence of a Ag~__n__~^0^/Ag~__n__~^+^ redox couple facilitates a

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