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Wolff Rearrangement of α-Diazoketones Using in Situ Generated Silver Nanoclusters as Electron Mediators

✍ Scribed by Sudrik, Surendra G.; Sharma, Jadab; Chavan, Vilas B.; Chaki, Nirmalya K.; Sonawane, Harikisan R.; Vijayamohanan, Kunjukrishna P.

Book ID
126231972
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
70 KB
Volume
8
Category
Article
ISSN
1523-7060

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Silver Nanocluster Redox-Couple-Promoted Nonclassical Electron Transfer: An Efficient Electrochemical Wolff Rearrangement of α-Diazoketones
✍ Surendra G. Sudrik; Nirmalya K. Chaki; Vilas B. Chavan; Sambhaji P. Chavan; Subh 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 110 KB

## Abstract In this work we report the unique electrocatalytic role of benzoic acid protected silver nanoclusters (Ag~__n__~, mean core diameter 2.5 nm) in the Wolff rearrangement (Scheme 1) of α‐diazoketones. More specifically, the presence of a Ag~__n__~^0^/Ag~__n__~^+^ redox couple facilitates a