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ChemInform Abstract: Microwave Specific Wolff Rearrangement of α-Diazoketones and Its Relevance to the Nonthermal and Thermal Effect.

✍ Scribed by Surendra G. Sudrik; Sambhaji P. Chavan; K. R. S. Chandrakumar; Sourav Pal; Sadgopal K. Date; Subhash P. Chavan; Harikisan R. Sonawane

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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Intramolecular O-H Insertion Reaction of Azido Substituted Diazoesters and Its Relevance to the Mechanism of the Allylic Azide Rearrangement. -The Rh(II)-catalyzed decomposition of diazoesters (I), (IV), and (VII) affords the expected O-H insertion products as a mixture of diastereomeric furanones.