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Evidence for multiple-state emission from ruthenium(II) complexes

✍ Scribed by R.W. Harrigan; G.D. Hager; G.A. Crosby

Publisher: Elsevier Science
Year: 1973
Tongue: English
Weight: 385 KB
Volume: 21
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(73)80290-8

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✦ Synopsis

Temperature dependence mczurements

(2-77OK) of both the Lifetime of decay and the quantum yield of luminescence for the tris(2,2'.bipyridine)ruthcnium(ll) cation show the emission to originate from several levels. Energy level gaps, rate constants, and quantum yields have been measured for each individual level, and group theoretical symmchy assignments have been made on the basis of a proposed clcctronic coupling model.

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