Rotationatly resolved fluorescence excitation spectra of two vibronic bands at AE= 410.5 and 414.9 cm -l in the S l ~ S O electronic transition of trans-l-naphthol have been recorded and analyzed. The analysis reveals that the in-plane transition dipole moment of the 410 cm-1 band makes an angle of
Fluorescence of DPH derivatives. Evidence for emission from S2 and S1 excited states
โ Scribed by P.C. Alford; T.F. Palmer
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 478 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Absorption, fluorcsccncc cwtauon and emwon spectra, quantum yields, and fluorescence decay times have been measurcd for several derwauvcs of all-trans 1,6dlphenyl-1,3,5hexatriene (DPH) III a number of solvents. Emlsslon occurs from the low-lymg IA: state and the I B,* which IS at shghtly hgher energy. Accepted models for Ihe photophysics of DPH are shown 10 be mad-cquaw.
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