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Near-infrared emissions from the 1Δg and 1Σ+g states of S2

✍ Scribed by I. Barnes; K.H. Becker; E.H. Fink

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
239 KB
Volume
67
Category
Article
ISSN
0009-2614

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✦ Synopsis

In a discharge flow system O2(1A~) sensitized chemiluminescence has been observed from the two low lying lAg and 11C~ states of $2 in the wavelength re~ion 1.0 to 1.8 ~tm. The hitherto unknown energies of the two states were found to be 5730 -+ 20 crn -1 and 7961 -+ 15 cm -l, respectively. Due to the near energy resonance (AE ~ 79 cm -1 ) between the lAg state of 02 and the 1 ~g + state of $2 effective energy exchange between both molecules is found to occur.

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