CAS SCF Cl calculations for the 3Σ−g, 1Σ+g, 3Σ+u, and 5Δu states of Sc2
✍ Scribed by Stephen P. Walch; Charles W. Bauschlicher Jr.
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 578 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0009-2614
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Polarization labelling spectroscopy is applied to study excited states of K2 lying in the energy range 23800-25800 cm-' above the bottom of the ground state. The two observed states are identified as 3 'l&(4 'S+S 'P) and 3 '&/ (4 \*S+ 3 'D). Molecular constants are derived for both states from a Dun
The \(a^{3} \Sigma_{\mathrm{u}}^{+}\left(a_{1} 1_{\mathrm{u}}\right) \rightarrow X^{1} \Sigma_{\mathrm{B}}^{+}\left(X 0_{\mathrm{B}}^{+}\right)\)near-infrared transition of \(\mathrm{Bi}_{2}\), which was recently observed in the thermal emission spectrum of bismuth vapor by Barrow et al. (Chem. Phys