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Multiple state emission from rhodium(I) and iridium(I) complexes

✍ Scribed by W.A. Fordyce; H. Rau; M.L. Stone; G.A. Crosby

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
393 KB
Volume
77
Category
Article
ISSN
0009-2614

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✦ Synopsis

The effect of temperature (2-lOOK) on the emlsslon spectra and llfetlmes of [hl(2= phos)~lCl04 (Xl = Rh(I), Ir(l) 2= phos IS cls-1,2-bn_(&phenylphosphmo)ethylene) is mterpreted with a two-level spm-orblt-spht emlttmng marufolrl For [Lr(2=phos)z]C104, AC= 143cm-', ~(lower) = 999~~ and sfilqher) = 1 54 us. ror the rho&urn species, & = 3'J cm-', T(lower) = 5920 us, and T(Txghcr) = 20 3 GS * Research supported by AFOSR(NC)-OAR Grant SO-0038 * On leave from the Uruverslty of Hohenhelm, West Germany.

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