Complexes of Rhodium(I) and Iridium(I) with the Chiral Tridentate Phosphane Pigiphos: Structure and Reactivity Studies
✍ Scribed by Lukas Hintermann; Mauro Perseghini; Pierluigi Barbaro; Antonio Togni
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 201 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
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## Abstract It has been shown that 2 equiv. of 2,3,5,6‐tetraphenylphosphinine (**2**) react with [Rh(COD)~2~][BF~4~] to yield the bis(η^1^‐phosphinine)Rh^I^ complex **6**, whose X‐ray crystal structure is presented. On the other hand, 2,6‐bis(trimethylsilyl)phosphinines **4** and **5** react with R
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