Evidence for ligand isomerism in the palladium(II) complex of 1,4,7-trithiacyclodecane
β Scribed by Chandrasekhar, S.; McAuley, A.
- Book ID
- 126075460
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 445 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
## ~ [ I ] The I8 n-electron system of the porphyrins can be viewed as a doubly bridged diazd[ 1 Blannulene or as a tetraaza[l6]annulene dianion. The formuldtion ds a dianion is in agreement with, among other characteristics, the spectroscopic properties of the metal complexes of the porphyrins: c
Evidence for a coordination of p-benxoquinone to palladium in [4-acetoxy-n3-(1,2,3)-cyclohexenyllpalladium(II) complexes was provided by changes of the 'H NMR chemical shift values of the r-ally1 protons and a decrease of the spin-lattice relaxation time constant for the p-benxoquinone protons. We h
Single crystals of the new bromo-bridged onedimensional Pd"-Pd'" mixed-valence complex [ Pd( chxn)\*Br] Br2 (chxn = trans-1,2-cyclohexanediamine) have been prepared. ESR spectra, resonance Raman spectra, reflection spectra and conductivities are reported. The results are interpreted as evidence for