𝔖 Bobbio Scriptorium
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Weak Pd…S Interactions in Palladium(II) Complexes with 1,4,7-Trithiacyclononane as Ligand

✍ Scribed by Prof. Dr. Karl Wieghardt; Dipl.-Chem. Heinz-Josef Küppers; Dr. Eleonore Raabe; Prof. Dr. Carl Krüger


Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
335 KB
Volume
25
Category
Article
ISSN
0044-8249

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✦ Synopsis


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[ I ] The I8 n-electron system of the porphyrins can be viewed as a doubly bridged diazd[ 1 Blannulene or as a tetraaza[l6]annulene dianion. The formuldtion ds a dianion is in agreement with, among other characteristics, the spectroscopic properties of the metal complexes of the porphyrins: cf.


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## Abstract This paper reports the synthesis of a family of mononuclear complexes [Fe(L)]X~2~ (X=BF~4~, PF~6~, ClO~4~) with hexadentate ligands L=Hpy‐DAPP ({bis[__N__‐(2‐pyridylmethyl)‐3‐aminopropyl](2‐pyridylmethyl)amine}), Hpy‐EPPA ({[__N__‐(2‐pyridylmethyl)‐3‐aminopropyl][__N__‐(2‐pyridylmethyl)