Evidence for a Cooperative Intramolecular Transition in Poly-L-proline
β Scribed by Gornick, F.; Mandelkern, L.; Diorio, A. F.; Roberts, D. E.
- Book ID
- 126333006
- Publisher
- American Chemical Society
- Year
- 1964
- Tongue
- English
- Weight
- 835 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The synthetic polymer poly-L-proline exists in two conformational forms, I and 11, the structures of which have been elucidated by x-ray crystallography.'-3 Form I is a right-handed helix with all peptide bonds in the cis configuration, and is stable in pyridine and aliphatic alcohols. Form I1 is a
## Abstract The kinetics for the __cis__β__trans__ isomerization of longβchain polyβLβproline has been studied as a function of pressure, temperature, and solvent composition in the acetic acid + __n__βpropanol solvent system. Our complete kinetic curves were fitted by Monte Carlo techniques, and r