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Evidence for a Cooperative Intramolecular Transition in Poly-L-proline

✍ Scribed by Gornick, F.; Mandelkern, L.; Diorio, A. F.; Roberts, D. E.


Book ID
126333006
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
835 KB
Volume
86
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Equilibrium and kinetic studies of the c
✍ JΓΌrgen Engel πŸ“‚ Article πŸ“… 1966 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 240 KB πŸ‘ 2 views

The synthetic polymer poly-L-proline exists in two conformational forms, I and 11, the structures of which have been elucidated by x-ray crystallography.'-3 Form I is a right-handed helix with all peptide bonds in the cis configuration, and is stable in pyridine and aliphatic alcohols. Form I1 is a

Kinetics for the transition between cis-
✍ Joseph M. Rifkind πŸ“‚ Article πŸ“… 1970 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 849 KB

## Abstract The kinetics for the __cis__‐__trans__ isomerization of long‐chain poly‐L‐proline has been studied as a function of pressure, temperature, and solvent composition in the acetic acid + __n__‐propanol solvent system. Our complete kinetic curves were fitted by Monte Carlo techniques, and r