Order-order transition in a macromolecular system—poly-L-proline I and II
✍ Scribed by R C Agnihotri; C Mehrotra; V D Gupta; Vandana Srivastava
- Book ID
- 112911523
- Publisher
- Springer-Verlag
- Year
- 1981
- Tongue
- English
- Weight
- 386 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0304-4289
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The synthetic polymer poly-L-proline exists in two conformational forms, I and 11, the structures of which have been elucidated by x-ray crystallography.'-3 Form I is a right-handed helix with all peptide bonds in the cis configuration, and is stable in pyridine and aliphatic alcohols. Form I1 is a
## Abstract The conformational transition of Form II → Form I of Poly‐L‐proline and the intermolecular aggregation of the product Form I during and after the transition in the HOAc‐propanol mixture solvent were studied, the ratio of HOAc:propanol being changed as 1:9, 1:6, and 1:4 v/v. For the stud
## Abstract The far infrared spectra of poly(L‐proline) I (190–35 cm^−1^) and II (400–35 cm^−1^) were obtained in the solid state at both 300° and 110°K. A significant difference in the region below 100 cm^−1^ was observed. A very intense band located at 60 cm^−1^ in the infrared spectrum of form I