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Equilibrium and kinetic studies of the cooperative I ⇌ II transition in poly-L-proline

✍ Scribed by Jürgen Engel

Publisher
Wiley (John Wiley & Sons)
Year
1966
Tongue
English
Weight
240 KB
Volume
4
Category
Article
ISSN
0006-3525

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✦ Synopsis

The synthetic polymer poly-L-proline exists in two conformational forms, I and 11, the structures of which have been elucidated by x-ray crystallography.'-3 Form I is a right-handed helix with all peptide bonds in the cis configuration, and is stable in pyridine and aliphatic alcohols. Form I1 is a left-handed helix having all peptide bonds in the trans configuration, and is stable in water, acetic acid, formic acid, and benzyl alcoh01.~~~

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