For the first time, the (E)-1,2-difluoro-2-(pentafluorok 6 -sulfanyl)ethenyl group has been bonded to k 3 r 3 phosphorus using a Grignard reagent. Similar phosphorus derivatives containing the (Z)-1,2,3,3,3-pentafluoropropenyl moiety were also synthesized for comparison. In three cases, hexafluoroac
Ethylidenphosphoran-Ethenylfluorphosphoran-(λ5σ4P-λ5σ5P)-Umlagerung
✍ Scribed by Heine, Joachim ;Röschenthaler, Gerd-Volker
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1987
- Tongue
- English
- Weight
- 163 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0009-2940
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The oxidation of the 1,3-diaza-4,6-diphosphorine 1 with tetrachloroorthobenzoquinone 2 led, unexpectedly, to the fortiration of 1,5-di?i~thyl-2,2-bis(dintethylan iin 0)-4,4,4,4-bis-(tetrachloro-o-pheny1enedioxa)-1,5diaza-2,4-X4, X6-diphosphorinaned-one 4, containing two phosphorus atoms of opposite
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