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λ3σ3P and λ5σ5P derivatives of (E)-1,2-difluoro-2-(pentafluoro-λ6-sulfanyl)ethylene and (Z)-1,2,3,3,3-pentafluoropropylene

✍ Scribed by Holger Wessolowski; Andreas Gentzsch; Gerd-Volker Röschenthaler; Gary L. Gard

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
151 KB
Volume
8
Category
Article
ISSN
1042-7163

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✦ Synopsis

For the first time, the (E)-1,2-difluoro-2-(pentafluorok 6 -sulfanyl)ethenyl group has been bonded to k 3 r 3 phosphorus using a Grignard reagent. Similar phosphorus derivatives containing the (Z)-1,2,3,3,3-pentafluoropropenyl moiety were also synthesized for comparison. In three cases, hexafluoroacetone was added to form 4

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