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Phosphavinylidene(oxo)phosphorane Mes*P(O)=C=PMes*: A Diphosphaallene Featuring λ5σ3- and λ3σ2-Phosphorus Atoms

✍ Scribed by Raluca Septelean; Henri Ranaivonjatovo; Gabriela Nemes; Jean Escudié; Ioan Silaghi-Dumitrescu; Heinz Gornitzka; Luminita Silaghi-Dumitrescu; Stéphane Massou


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
128 KB
Volume
2006
Category
Article
ISSN
1434-1948

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Phosphavinylidene(oxo)phosphorane Mes*P(
✍ Raluca Septelean; Henri Ranaivonjatovo; Gabriela Nemes; Jean Escudié; Ioan Silag 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 77 KB

## Abstract **The cover picture shows** the P=C=P backbones of stable, neutral diphosphaallenes along with the publication year of the first example reported for given coordination numbers of the phosphorus atoms. Since the synthesis of hexaphenylcarbodiphosphorane (Ph~3~P=C=PPh~3~), a σ^4^,σ^4^‐di