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Ethylene polymerization process with a highly active Ziegler-Natta catalyst: 1. Kinetics

✍ Scribed by L.L Böhm

Book ID
103350284
Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
977 KB
Volume
19
Category
Article
ISSN
0032-3861

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A soluble ethylene catalyst were obtained by mixing a methylene dichloride solution of dichlorobislT-cyclopentadienyl) titanium (Cp2TiCI2) with a heptane solution of ethylaluminium sesquichloride (AlzEt3C13) or of diethylaluminium chloride {AIEt2CI). Ethylene was polymerized using these catalysts; t

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Ethylene polymerization reactions with Ziegler–Natta catalysts. I. Ethylene polymerization kinetics and kinetic mechanism
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Kinetics of ethylene homopolymerization reactions and ethylene/1-hexene copolymerization reactions using a supported Ziegler-Natta catalyst was carried out over a broad range of reaction conditions. The kinetic data were analyzed using a concept of multicenter catalysis with different centers that r