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Ethylene-Bridged Bissulfoximines in Copper-Catalyzed Enantioselective Hetero-Diels--Alder Reactions

✍ Scribed by Carsten Bolm; Marinella Verrucci; Oliver Simic; Christian P. R. Hackenberger

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 81 KB
Volume: 347
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.200505104

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✦ Synopsis

Abstract

Ethylene‐bridged bissulfoximines were applied as chiral ligands in copper‐catalyzed enantioselective hetero‐Diels–Alder reactions. After optimization of the reaction conditions, products with up to 99% ee were obtained.

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