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Pseudo-C3-Symmetric Trisoxazolines as Ligands in Copper Catalyzed Enantioselective Diels—Alder Reaction.

✍ Scribed by Jian Zhou; Yong Tang

Publisher
John Wiley and Sons
Year
2004
Weight
143 KB
Volume
35
Category
Article
ISSN
0931-7597

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C1-Symmetric Versus C2-Symmetric Ligands
C1-Symmetric Versus C2-Symmetric Ligands in Enantioselective Copper–Bis(oxazoline)-Catalyzed Cyclopropanation Reactions
✍ José M Fraile; José I. García; Anja Gissibl; José A. Mayoral; Elísabet Pires; Ol 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 496 KB

## Abstract A thorough experimental and theoretical study of the enantioselective cyclopropanation of alkenes catalyzed by chiral bis(oxazoline)– and azabis(oxazoline)–copper complexes, which comprise a new family of ligands that lack __C__~2~ symmetry, has been conducted. Surprisingly high enantio