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C1-Symmetric Sulfoximines as Ligands in Copper-Catalyzed Asymmetric Mukaiyama-Type Aldol Reactions

✍ Scribed by Martin Langner; Carsten Bolm

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
141 KB
Volume
116
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES

C1-Symmetric Aminosulfoximines in Copper
C1-Symmetric Aminosulfoximines in Copper-Catalyzed Asymmetric Vinylogous Mukaiyama Aldol Reactions
✍ Marcus Frings; Iuliana Atodiresei; Yutian Wang; Jan Runsink; Gerhard Raabe; Cars πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 376 KB

## Abstract Vinylogous Mukaiyama‐type aldol reactions have been catalyzed by a combination of Cu(OTf)~2~ and readily available __C__~1~‐symmetric aminosulfoximines. After a fine‐tuning of the reaction conditions and an optimization of the modularly assembled ligand structure, high stereoselectiviti