ChemInform Abstract: Enantioselective Copper Catalyzed Diels—Alder Reaction Using Chiral Quinoline-Phosphine Ligand.

✍ Scribed by Jean Michel Brunel; Beatriz Del Campo; Gerard Buono

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 30 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199912040

✦ Synopsis

Enantioselective Copper Catalyzed Diels-Alder Reaction Using Chiral Quinoline-Phosphine Ligand. -A highly enantioselective Diels-Alder reaction between 3-acryloyl-1,3-oxazolidin-2-one (I) and cyclopentadiene is achieved using a new Cu(II) catalyst generated from Cu(OTf) 2 and chiral quinoline-phosphine ligands. -(BRUNEL,