Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.069 wR factor = 0.157 Data-to-parameter ratio = 12.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Ethyl (Z)-3-bromo-2-[(tert-butoxycarbonyl)amino]-3-phenylacrylate
✍ Scribed by Jones, Peter G. ;Jäger, Stefan
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 263 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 273 K Mean '(C±C) = 0.003 A Ê R factor = 0.056 wR factor = 0.162 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The reaction of -(N-t-butoxycarbonyl)amino-,-ethylenic esters with OsO 4 yields the corresponding ,-dihydroxy compounds with good diastereoselectivity. The crystal structure of the major stereomer, (2SR,3SR,4RS)-Me 2 CHC\\forcelb]H(NHCO 2 t Bu)CHOHCHOHCO 2 t Bu, C 16 H 31 NO 6 , shows that the relat
The absolute configuration has been determined for the title compound, C 14 H 18 N 2 O 5 S, a bicyclic aromatic building block which can act as a rigid fluorescence marker in peptide backbones. In the crystal packing, the two independent molecules of the asymmetric unit are aligned in an antiparalle