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(3R)-Meth­yl 6-tert-butoxy­carbonyl­amino-5-oxo-2,3-dihydro-5H-1,3-thia­zolo[3,2-a]pyridine-3-carboxyl­ate

✍ Scribed by Seger, Harald ;Stempfhuber, Sabine ;Zabel, Manfred ;Marsch, Michael ;Geyer, Armin ;Harms, Klaus

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
154 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The absolute configuration has been determined for the title compound, C 14 H 18 N 2 O 5 S, a bicyclic aromatic building block which can act as a rigid fluorescence marker in peptide backbones. In the crystal packing, the two independent molecules of the asymmetric unit are aligned in an antiparallel manner as dimers which are stabilized by antiparallel intermolecular N-HÁ Á ÁO C hydrogen bonds. In addition, there are weak intermolecular C-HÁ Á ÁO interactions.

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