Ethyl (2Z)-2-(2-chlorobenzylidene)-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5H-1,3-thiazolo[3,2-a]pyrimidine-6-carboxylate
✍ Scribed by Jotani, Mukesh M. ;Baldaniya, Bharat B.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 238 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title compound, C 23 H 19 ClN 2 O 3 S, the central pyrimidine ring is significantly puckered, assuming an intermediate conformation between an envelope and a screw-boat form. Short intermolecular C-HÁ Á ÁO, C-HÁ Á Á andstacking interactions contribute to the stability of the crystal packing.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.040 wR factor = 0.126 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C~25~H~24~N~2~O~3~S~3~, was crystallized from a methanol–acetone mixture. The monoclinic structure features one molecule in the asymmetric unit. The crystal packing is stabilized by π stacking.