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Estimations of OH radical rate constants from H-atom abstraction from CH and OH bonds over the temperature range 250-1000 K

✍ Scribed by Roger Atkinson

Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
644 KB
Volume
18
Category
Article
ISSN
0538-8066

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✦ Synopsis

Rate constants for overall H-atom abstraction by hydroxyl radicals from C -H and 0 -H bonds are estimated for alkanes, haloalkanes, aldehydes, ketones, ethers, alcohols, nitriles, and nitrates over the temperature range 250-1000 K. These estimated rate constants utilize the modified Arrhenius expression k = A'T'e -E IT in combination with the recommendations given in the recent review and evaluation of OH radical kinetics of Atkinson 111. This estimation procedure gives good agreement, generally to within better than a factor of 2, of the estimated rate constants with these recommendations.

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