Estimation of experimental parameters for the determination of ruthenium by flame atomic absorption spectroscopy
✍ Scribed by Z Benzo; J Salas; P.W Araujo; A Camardiel; N Carrión
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 172 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0169-7439
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✦ Synopsis
The theory of design of experiments was applied to study some factors which may influence the flame atomic absorption determination of ruthenium. The estimation of the magnitude of the main effects and some two factor interactions on the sensitivity of ruthenium was studied in two buffer solutions: cerium and lanthanum. The flame type, the presence of iron, silicon and acid at some levels studied as well as some two factor interactions have been found to have an important influence on ruthenium sensitivity by this technique, depending on the buffer used.
📜 SIMILAR VOLUMES
Interferences of the matrix elements of glass ceramics (Al, Mg, Na and Si) on the titanium signal obtained by atomic absorption spectrometry with a nitrous oxide/acetylene flame were studied by means of experimental design. Quadratic polynomials were chosen as the model; full factorial designs with
Magrtesitrm 21 28 2 li G ml\ 4.5 l/nlin 25 I/tnin .---I\_- Water was first sprayed through the flame followed by the calcium or magncsium solutions. This operation was repeated after each absorption measurement. Under these conditions, the sensitivity for calcium was 0.5 p.p,m., and for magnesium,