Estimation of electron-transfer contributions in reactions of alkyl bromides with (trimethyltin)sodium
โ Scribed by Kuivila, Henry G.; Smith, Gary F.
- Book ID
- 120563223
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 294 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
It has been established by chemical (2a) and CIDNP (3,4) techniques that some transition metal salts catalyze the reaction of Grignard reagents with alkyl halides by a mechanism involving free radicals. Such catalysis is probably responsible for the Wurtz coupling side reaction which lowers the yiel
Evidence for a radical process in' the reaction of lithium alkoxides with alkyl iodides was obtained by the observation of cyclization of appropriate radical probes, by the trapping of radicals, and by EPR spectroscopic observations relating to the one electron donor properties of alkoxides.