Reaction of .pi.-2-methallylnickel bromide with methylbenzoquinones. Evidence for electron transfer
β Scribed by Hegedus, L. S.; Waterman, E. L.
- Book ID
- 127299327
- Publisher
- American Chemical Society
- Year
- 1974
- Tongue
- English
- Weight
- 339 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Evidence for a radical process in' the reaction of lithium alkoxides with alkyl iodides was obtained by the observation of cyclization of appropriate radical probes, by the trapping of radicals, and by EPR spectroscopic observations relating to the one electron donor properties of alkoxides.
Utilization of a triptoxy radical probe in the with 2,3,3-trimethyl-2-butyl peroxybenzoate indicates reaction decreases in the order B-BuLi>B-BuMgCl>PhMgBr. reactions of organometallic compounds that the radical character of the Peroxides may react with nucleophiles either by nucleophilic displaceme