ESR study on radical polymerization of styrene
โ Scribed by Bunichiro Yamada; Masakazu Kageoka; Takayuki Otsu
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 287 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0170-0839
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The polymerization of diisopropyl itaconate (DIPI) initiated with dimethyl 2,2'-azobisisobutyrate(MAIB) was investigated kinetically in benzene. The polymerization rate (Rp) was expressed by R v = k[MAIB]ยฐ46[I)IPI] 16 at 50 ยฐ. The overall activation energy of the polymerization was calculated to be
## Abstract Monocyclopentadienyltitanium trichloride (CpTiCl~3~) was directly immobilized on silica surface. The resulting CpTiCl~3~/SiO~2~โMAO was investigated in view of its suitability for syndiospecific polymerization of styrene using ESR spectroscopy. Polymerization results show that both the