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ESR study of the radical polymerization of styrene

โœ Scribed by Bunichiro Yamada; Masakazu Kageoka; Takayuki Otsu

Publisher
Springer
Year
1992
Tongue
English
Weight
341 KB
Volume
29
Category
Article
ISSN
0170-0839

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Kinetic and ESR studies on radical polym
Kinetic and ESR studies on radical polymerization. Radical polymerization of diisopropyl itaconate
โœ T. Sato; Y. Hirose; M. Seno; H. Tanaka; N. Uchiumi; M. Matsumoto ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 391 KB

The polymerization of diisopropyl itaconate (DIPI) initiated with dimethyl 2,2'-azobisisobutyrate(MAIB) was investigated kinetically in benzene. The polymerization rate (Rp) was expressed by R v = k[MAIB]ยฐ46[I)IPI] 16 at 50 ยฐ. The overall activation energy of the polymerization was calculated to be