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ESR study of N-acyl-N-alkyl nitroxide radicals from photolysis of N-nitrosoamides

✍ Scribed by Elio Flesia; Jean-Marie Surzur; Paul Tordo

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
360 KB
Volume
11
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

A new method of generation of N‐acyl‐N‐alkyl nitroxide radicals by photolysis of N‐nitrosoamides is described. ESR parameters are reported for 17 radicals of the general formula RCON(R′)O^.^; the high resolution obtained allows conformational analysis which shows a preferred trans conformation around the CON bond and hindered rotation around the NR′ σ‐bond.

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