ESR study of irradiated single crystals of amino acids—II: l-aspartic acid
✍ Scribed by Mariko Ogawa; Kenkichi Ishigure; Keichi Oshima
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 363 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0146-5724
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X-Irradiation of single crystals of methylene diarsonic acid gives rise to a variety of radicals which have been identified by ESR. spectroscopy: (OH),As(O) CHAs(0) (OH),, -0As (OH)2CH2As (O)(OH),, As03--and (0H)As (0)CH2As (0) (OH)2. The spin densities have been obtained from the 75As-hyperfine ten
## Abstract The conformation of poly(α‐L‐aspartic acid) was investigated on a sample in which β‐bonds were not detected. CD and ir spectroscopy showed that poly(α‐L‐aspartic acid) passes through a conformational change induced by changes of the degree of ionization that is accompanied by precipitat