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Conformational study of poly(α-L-aspartic acid)

✍ Scribed by V. Saudek; Š. Štokrová; P. Schmidt

Publisher
Wiley (John Wiley & Sons)
Year
1982
Tongue
English
Weight
538 KB
Volume
21
Category
Article
ISSN
0006-3525

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✦ Synopsis

Abstract

The conformation of poly(α‐L‐aspartic acid) was investigated on a sample in which β‐bonds were not detected. CD and ir spectroscopy showed that poly(α‐L‐aspartic acid) passes through a conformational change induced by changes of the degree of ionization that is accompanied by precipitation; the precipitate is probably highly helical. The change was also detected by potentiometric titration.

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