𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ESR. Study of an X-Irradiated Single Crystal of Methylene Diarsonic Acid

✍ Scribed by Michel Geoffroy; Antoine Llinares

Publisher
John Wiley and Sons
Year
1981
Tongue
German
Weight
403 KB
Volume
64
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

X-Irradiation of single crystals of methylene diarsonic acid gives rise to a variety of radicals which have been identified by ESR. spectroscopy: (OH),As(O) CHAs(0) (OH),, -0As (OH)2CH2As (O)(OH),, As03--and (0H)As (0)CH2As (0) (OH)2. The spin densities have been obtained from the 75As-hyperfine tensors. An additional species -probably a radical anion localized on a pentacoordinated arsenicis also detected after annealing at room temperature. The radiation damage process is discussed.

πŸ“œ SIMILAR VOLUMES

ESR. Study of the Ph3Γ…sBr-Radical Trappe
ESR. Study of the Ph3Γ…sBr-Radical Trapped in an X-Irradiated Single Crystal of Ph3As+CH3Brβˆ’
✍ Michel Geoffroy; Antoine Llinares πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 German βš– 333 KB

Ph~3~Γ…sBr is trapped in an X‐irradiated single crystal of Ph~3~As^+^CH~3~Br^βˆ’^. The g‐tensor, the ^75^As and ^79^Br magnetic hyperfine tensors and the ^79^Br quadrupolar interaction tensor are obtained at room temperature. They show that the structure of this arsoranyl radical is intermediate betwee

ENDOR studies of X-irradiated naphthalen
ENDOR studies of X-irradiated naphthalene single crystals
✍ U.R. BΓΆhme; H.C. Wolf πŸ“‚ Article πŸ“… 1972 πŸ› Elsevier Science 🌐 English βš– 562 KB

Detailed ENDOR studies in the crhydronaphthyl radical have led to the determination of spin density distribution, hyperfme principal axes and values of the dipole-dipole interaction of all CH and CH? protons in the radical. Mirror image a-hydronaphthyl radicals show different concentrations because