Esr spectra of some radical cations of fluorinated hydrocarbons
โ Scribed by P.H.H. Fischer; H. Zimmermann
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 201 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
ES12 spectra observed at 120 Kin ririadialcd solid solutions of PFs in neopentane and AsFs in SF6 are asclibcd to the radical ions PF< and AsFz in which the unpaired electron interacts strongIF with the central nucleus nnd with four equivalent 191z nuclei. Hyperfine interaction with the filth 19F nu
Radical cations of both chlorotrifluoroethylene and bromotrifluorocthylene produced by y-irradiation of solid solutions of halocarbon matrices were detected and identified by ESR. The experimental spin density distributions strongly suggest that these radical cations have a planar structure with the