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ESR spectra and structures of radical cations of chlorotrifluoroethylene and bromotrifluoroethylene

โœ Scribed by K. Ohta; M. Shiotanp; J. Sohma

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
571 KB
Volume
140
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Radical cations of both chlorotrifluoroethylene and bromotrifluorocthylene produced by y-irradiation of solid solutions of halocarbon matrices were detected and identified by ESR. The experimental spin density distributions strongly suggest that these radical cations have a planar structure with the unpaired electron in the bonding x orbital of a" in C, symmetry.

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