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ESR spectra and structure of the n-butane and n-hexane radical cations

✍ Scribed by Jih Tzong Wang; Ffrancon Williams

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 453 KB
Volume: 82
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85133-0

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✦ Synopsis

We&resolved ESR spectra of the n-butane and n-hexane radicaI cations have been generated, each spectrum showing a I : 2 : 1 triplet and a detarIed substructure. The resufts are mterpreted in terms of an ag singly occupied MO (oC__C UC-H,) which is delocabzed over the extended carbon chain (C2b symmetry) and two axial hydrogens.

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